
I've read about people having problems with Cayenne, Habanero or other "hot" chilies or sauces and as a Chef who specializes in Mexican fare, plus I now live in Mexico too, I can give you a very easy and efficient remedy to ease the burning from peppers. Also, it doesn't matter if the burning is in your mouth, lips, face (from touching it with your hands after handling peppers) or hands, it works:
Put a little salt on the palm of your left hand, wet the tip of your right index finger in your mouth slightly and dip it in the salt and place it UNDER your tongue (sublingual) in the tender area on your jaw and not ON the underside of the tongue. Relief is very quick, easy to do, you can do it anywhere (like a restaurant) and works for everyone plus you can find salt everywhere.