Replied by Art (California) on 02/29/2024
Hi Walt, I use a heated magnetic stirring device when making colloidal silver and my water temp is heated and this means that steam vapor is generated during the entire run of the batch. I use heat to help increase the rate of ion reduction to silver nanoparticles of small size in the 12 - 20 nm range.
A device such as the one you linked to that sits over the water seems very handy, but if you run your batch with heated water as I do, the steam will take a toll on whatever electronics and connections that are inside the box and shorten the useable life of the generator. Even if the device is fairly well sealed, the temperature differentials that the device will be exposed to can potentially cause internal condensation which will have a similar negative effect.
I have a SilverTron and it sits off to the side of the beaker and heated stirring plate and is not exposed to any of the steam emanating from the beaker. It has lasted many years through hundreds of batches. Unfortunately the SilverTron is no longer available.
The generator you linked to does appear to have current regulation which is needed in order to make consistent batches so that is a big plus.
If you plan to use heated water, it appears this unit can be fairly easily adapted so it does not sit on the beaker which can potentially significantly extend the useable life of the unit.
The following scientific article explains why raising the temperature is useful in achieving faster reduction of the silver ions and smaller particle size of AgNPs:
https://www.sciencedirect.com/science/article/pii/S1878535217301727#:~:text=Khalil et al., of AgNPs with small size.
Here is a relevant article quote :
' With regard to the effect of reaction temperature, most of reports revealed that the size of nanoparticles become smaller with the increased temperature. For example, Khalil et al. (2014) synthesized silver nanoparticles using olive leaf extract and they reported that increasing of the reaction temperature led to a rapid reduction rate of the Ag+ ions and the subsequent homogeneous nucleation of silver nuclei-allowing for the formation of AgNPs with small size. '
Art
Back to Colloidal Silver Q&A